Journal of the Taiwan Institute of Chemical Engineers, Your Mendeley pairing has expired. Carbon dioxide (chemical formula CO 2) is a colorless gas with a density about 53% higher than that of dry air. Results and Discussion The total pressure of amine-H 2O-CO 2 system is P t=P meas-P N 2, where P meas is the measured pressure and P N 2 is the N 2 partial pressure; N 2 was assumed to be an ideal gas so P =P, T(K) T (K) , 0 stands for the initial condition. 2 Predicting thermal conductivity of carbon dioxide using group of data-driven models. Carbon dioxide reacts with water. You have to login with your ACS ID befor you can login with your Mendeley account. Solubility of air in water - expressed as ratio of absorbed air volume to water volume: G. Houghton, A.M. McLean, P.D. These metrics are regularly updated to reflect usage leading up to the last few days. Get article recommendations from ACS based on references in your Mendeley library. After proton transfer from water to an oxygen of the CO 2 unit, carbonic acid is formed. It occurs naturally in Earth's atmosphere as a trace gas.The current concentration is about 0.04% (412 ppm) by volume, having risen from pre-industrial levels of 280 ppm. This water is … Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Carbon dioxide molecules consist of a carbon atom covalently double bonded to two oxygen atoms. The pH is about 5.6 at concentration 380ppm; about the same as pure rainwater. The solubility is given for "pure water", i.e., water which contain only CO 2. and 0–100°c. ). Please reconnect. To this end, four back-propagation algorithms are applied in the MLP learning phase, while Particle Swarm Optimization (PSO), Differential Evolution (DE), Genetic Algorithm (GA), and Firefly Algorithm (FFA) are used to optimize the RBFNN and LSSVM control parameters. Find more information on the Altmetric Attention Score and how the score is calculated. The solubility of CO 2 in pure water was investigated under high-pressure conditions, from 7 to 12 MPa. Application of Artificial Intelligence-based predictive methods in Ionic liquid studies: A review. Department of Petroleum Engineering, Shahid Bahonar University of Kerman, Kerman 76169133, Iran, Département Etudes Thermodynamiques, Division Laboratoires, Sonatrach, Boumerdes 15003, Algeria, Departments of Geology and Environmental Engineering, University of Cincinnati, Cincinnati, Ohio 45221, United States, College of Construction Engineering, Jilin University, Changchun 130026, China. Biscardi. polarizability, size, hydrophobicity, etc. If Henry’s law is used to denote how the concentration will change with pressure, the following equation is used: [latex]\frac{P_1}{C_1} =\frac{P_2}{C_2}[/latex] Find more information about Crossref citation counts. O. E.R. Solubility of pure gases like. Citations are the number of other articles citing this article, calculated by Crossref and updated daily. In addition, the comparison results reveal that the LSSVM-FFA is the best paradigm to estimate the solubility of CO2 in pure water, as it outperforms the other proposed ML techniques as well as prior models. Opening of champagne or soda bottle at atmospheric pressure is a simple example of release of gases dissolved previously into liquid at higher pressure. Falola Yusuf, Teslim Olayiwola, Clement Afagwu. All carbonated beverages are bottled under pressure to increase the carbon dioxide dissolved in solution. The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Reactive chemical transport simulations of geologic carbon sequestration: Methods and applications. Solubility of Air in Water. This article is cited by https://doi.org/10.1016/j.icheatmasstransfer.2020.104825, https://doi.org/10.1016/j.fluid.2020.112898, https://doi.org/10.1016/j.ijhydene.2020.09.145, https://doi.org/10.1016/j.earscirev.2020.103265, https://doi.org/10.1016/j.jtice.2020.08.001. 3. At acidic pH's, CO2 is freely existent in the water as aqueous CO2 gas in the solution. Find more information about Crossref citation counts. CO2 dissolution in water at different pressure and temperature conditions is one of the most essential issues to CO2 geological sequestration in brine aquifers. As a result of breathing compressed air and being subjected to high pressures caused by water depth, the amount of nitrogen dissolved in blood and other tissues increases. Saturated concentrations of CO 2 were determined from expanding dissolved gas. CO 2 clathrate hydrate formed at temperatures below approximately 10 °C. If the diver returns to the surface too rapidly, the nitrogen forms bubbles in the blood as it becomes less soluble due to a decrease in pressure. The overall RMSE and R2 values for LSSVM-FFA are 0.3261 and 0.9930, respectively. When the bottle is opened, the pressure above the solution decreases. the Altmetric Attention Score and how the score is calculated. The solubility of calcite in aqueous solutions—I The solubility of calcite in water between 75° and 200° at CO2 pressures up to 60 atm. Answer is: 1) high pressure and low temperature. As a result, the solution effervesces and some of the carbon dioxide bubbles off. Since the Krichevsfcy-llinskaya equation was used to model the system, a correlation for the A parameter was also developed. Here is chart of pH as function of CO2 partial pressure: Figure 2. A wide-ranged database including temperature and pressure as inputs and CO2 solubility in pure water as output is utilized to develop the models, which are then compared with each other and also against existing models. Air dissolved in water contains approximately 35.6% oxygen compared to 21% in air. The carbon atom of CO 2 is electron poor with an oxidation state of IV. Please reconnect, https://doi.org/10.1021/acs.energyfuels.0c00114. Temperature varied between 2.5–20 °C. Your Mendeley pairing has expired. CO2 dissolution in water at different temperature and pressure conditions is of essential interest for various environmental, geochemical, and thermodynamic related problems. 5 3/4 H The results demonstrate that the prediction performance of the proposed models is quite satisfactory. Menad Nait Amar, Ashkan Jahanbani Ghahfarokhi, Noureddine Zeraibi. The electron rich oxygen of water donates an electron pair to the carbon. Please note: If you switch to a different device, you may be asked to login again with only your ACS ID. Recent Work in the Field of High Pressures. The reference Henry's constant was determined from 110 solubility data found in the literature for the CO 2 /H 2 O system over a temperature range of 298 to 523 K and a pressure range of 3.40 to 72.41 MPa. For example, HCl (g) reacts with water in the dissociation reaction and affects solubility, so Henry’s law cannot be used in this instance. To expand the prediction capability of the ML approaches, their control parameters are optimized by various techniques. the Altmetric Attention Score and how the score is calculated. 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